Turkish Journal of ChemistrySynthesis of novel tetraoxime derivative with hydrazone side groups and its metal complexes
1Department of Chemistry, Adnan Menderes University, 09010 Aydın-TURKEY
2Department of Chemistry, Ege University, 35040 Bornova, İzmir-TURKEY
Abstract: In this study, the synthesis of a novel tetraoxime (LH4) derivative containing hydrazone side groups, and its transition metal complexes with Ni(II), Cu(II), Co(II), and Zn(II) ions, were reported. The ligand was synthesized by reacting anti-glyoximehydrazine (GH2) with terephthaldialdehyde. Polymeric complexes with Ni(II) and Co(II) and binuclear complexes with Cu(II) and Zn(II) of this tetraoxime were isolated. Structural assignments were supported by a combination of 1H-NMR, 13C-NMR, HMQC, FT-IR, UV-Vis, thermogravimetric analysis (TGA), molar conductances, elemental analyses, and magnetic susceptibility.
Key Words: Tetraoximes, hydrazone, transition metal complexes
Turk. J. Chem., 35, (2011), 613-624.
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Other articles published in the same issue: Turk. J. Chem.,vol.35,iss.4.