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Turkish Journal of Chemistry

Synthesis of novel tetraoxime derivative with hydrazone side groups and its metal complexes

İlknur BABAHAN1, Hüseyin ANIL2, Nursabah SARIKAVAKLI1
1Department of Chemistry, Adnan Menderes University, 09010 Aydın-TURKEY
e-mail: ibabahan@adu.edu.tr
2Department of Chemistry, Ege University, 35040 Bornova, İzmir-TURKEY

Abstract: In this study, the synthesis of a novel tetraoxime (LH4) derivative containing hydrazone side groups, and its transition metal complexes with Ni(II), Cu(II), Co(II), and Zn(II) ions, were reported. The ligand was synthesized by reacting anti-glyoximehydrazine (GH2) with terephthaldialdehyde. Polymeric complexes with Ni(II) and Co(II) and binuclear complexes with Cu(II) and Zn(II) of this tetraoxime were isolated. Structural assignments were supported by a combination of 1H-NMR, 13C-NMR, HMQC, FT-IR, UV-Vis, thermogravimetric analysis (TGA), molar conductances, elemental analyses, and magnetic susceptibility.

Key Words: Tetraoximes, hydrazone, transition metal complexes

Turk. J. Chem., 35, (2011), 613-624.
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Other articles published in the same issue: Turk. J. Chem.,vol.35,iss.4.