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Turkish Journal of Chemistry

Synthesis and Structural Characterization of the 2-[(o-pyridyl)-sulfanylmethyl]-pyrimidine-silver(I) Complex [Ag2(opsp)2](NO3)2

Li-Rong WEN1,2, Ming LI2, Gui-Long ZNAO2, Xue-Mei LI2,
Ou-Yang PINGKAI1 and Shu-Sheng ZHANG2
1College of Science and Pharmaceutical Engineering, Nanjing University of Technology,
210009, Nanjing-CHINA
2College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology,
266042 Qingdao, Shandong-CHINA
e-mail: zhangshush@public.qd.sd.cn

Abstract: The new silver(I) complexe [Ag2(opsp)2](NO3)2 (1) was synthesized by the self-assembly of AgX (X = NO3-) with the versatile multidentate ligand opsp (opsp = 2-[(o-pyridyl)-sulfanylmethyl]- pyrimidine). X-ray single-crystal diffraction analyses show that 1 is dinuclear molecule. In 1, 1 opsp ligand acts in a bidentate mode with 2 nitrogen atoms from a pyridine ring and a pyrimidine ring coordinating to 2 Ag(I) atoms, and the Ag(I) center is 2-coordinated by 2 nitrogen atoms showing linear coordination geometry.

Key Words: Multidentate ligand; Silver(I) complex; Crystal structure; Dinuclear molecule

Turk. J. Chem., 29, (2005), 193-197.
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Other articles published in the same issue: Turk. J. Chem.,vol.29,iss.2.